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    • 专利摘要:
    METHOD FOR INTEGRATING A FIRST THERMAL PROCESS AND A SECOND THERMAL PROCESS. The present invention relates to methods of integrating one or more thermal processes with each other, in which the thermal processes to be integrated have different supply and demand criteria for thermal energy. The method involves the use of one or more thermal stores.
    公开号:BR112013003382B1
    申请号:R112013003382-7
    申请日:2011-08-12
    公开日:2020-11-10
    发明作者:Robert Morgan；Stephen Gareth Brett
    申请人:Highview Enterprises Limited；
    IPC主号:
    专利说明:

    Field of the Invention
    [0001] The present invention relates to the integration of thermal and thermodynamic energy storage devices and, in particular, cryogenic energy storage devices, with other colocalized thermal processes that generate heat or cold and can benefit, including economically, from the heat or cold transfer to or from the energy storage device. Background of the Invention
    [0002] Electricity distribution and transmission networks (or grids) need to balance electricity generation with consumer demand. This is usually achieved by modulating the generation side (supply side) by turning power stations on and off, and running some under reduced load. As most existing thermoelectric and nuclear stations are more efficient when run continuously at full load, there is an efficiency penalty on balancing the supply side of the electricity system in this way. The expected introduction of significant intermittent renewable generation capacity, such as wind turbines and solar collectors, will further complicate grid balance, creating uncertainty in the availability of parts of the generation fleet. A means of energy storage during periods of low demand for later use during periods of high demand, or during low output of intermittent generators, would be of important benefit in balancing the grid and providing security of supply.
    [0003] Power storage devices operate on a highly intermittent basis when there is a shortage of generation capacity in the transmission or distribution network. This can be signaled to the storage device operator at a high price for electricity in the local power market or by a request from the organization responsible for operating the network for additional capacity. In some countries, such as the United Kingdom, the network operator establishes a contract to provide support reserves for the network with operators of power plants with a quick start capacity. Such contracts can cover months or even years, but typically the time that the power supplier will operate (power generation) is very short. This is illustrated in Figure 1, which shows a typical operating profile for a storage device.
    [0004] WO 2007-096656 A1 and GB1100569.1 disclose Cryogenic Power Storage Devices (CPSDs) that use cryogenic fluids, such as liquid nitrogen or liquid air, as storage media to store energy as potential thermal energy to supply network support and power storage services for electricity transmission and distribution networks. The Cryogenic Energy System (CES) described in WO 2007-096656 A1 is a first type of Cryogenic Power Storage Device (CPSD) and is a fully integrated storage device that requires only electricity and, optionally, heat as an input. The cryogenic assembly described in GB1100569.1 is another type of Cryogenic Power Storage Device (CPSD) and is a simplified storage / power generation device that uses cryogenic fluid manufactured by a remote industrial gas liquefaction plant from the cryogenic assembly, the which is distributed to the cryogenic assembly site by either pipe or tanker. Both CPSDs described in the patent applications mentioned above benefit from receiving low-grade residual heat (hot thermal energy) from a colocalized process. In addition, both devices producing low temperature cold thermal energy (cold energy) can be beneficial for other users who require cold, for example, air conditioning (offices); cooling (such as a data center); freezing or refrigeration (such as a food processing plant).
    [0005] However, CPSDs operate only on an intermittent basis, such as when there is high consumer demand or low generation of intermittent renewables, and typically for 250 to 1,000 hours per year, and can be as low as <100 hours per year depending on application. This poses at least three problems for integrating the CPSD with a colocalized process, which typically operates on an ongoing basis. Firstly, the demand for residual heat is intermittent and so the overall use of residual heat, based on the peak thermal load, will be low and therefore inefficient. Second, the cold energy supply will still be intermittent and difficult to use efficiently in a colocalized process that operates on a continuous basis. Third, the heat transfer rate of the colocalized process may differ from the heat transfer rate required for optimal CPSD efficiency.
    [0006] These problems are still relevant for the integration of other thermal processes with each other, in which the thermal processes to be integrated have different supply and demand criteria. Intermittence of supply and / or demand can be on an hourly, daily, weekly, monthly, seasonal or yearly basis.
    [0007] Thermal storage can be integrated within an energy storage device, such as a cryogenic energy storage device, in order to optimize thermal performance. Other energy storage technologies, examples of which include, but are not limited to, adiabatic compressed air energy storage and Ericsson cycle technologies, can further benefit from integration with residual heat and the use of integrated thermal storage both within the device of storage and / or between the storage device and a colocalized process. Summary of the Invention
    [0008] The present invention provides a method for integrating a first thermal process and a second thermal process, in which the heat transfer rate of the first thermal process is different from the heat transfer rate of the second thermal process, the method comprises: providing a first thermal storage; loading the first thermal storage with the first thermal energy of the first thermal process by transferring the first thermal energy to the first thermal storage at a first energy transfer rate; and discharging the first thermal storage by transferring the first stored thermal energy from the first thermal storage to components of the second thermal process at a second energy transfer rate, where the second rate is different from the first rate.
    [0009] The present invention takes into account the provision of a method for integrating a first Cryogenic Power Storage Device (CPSD) with a second process, in which the second process provides hot thermal energy and / or receives cold thermal energy, and where the demand and supply of thermal energy from the first and second processes are out of phase and have a different rate of heat transfer. This inequality in demand and supply is caused, in many cases, by the second process that operates continuously, or at least almost continuously, or at a different time from the day of the CPSD process.
    [00010] The first thermal energy can comprise heat energy or cold energy.
    [00011] The step of unloading the first thermal storage can be carried out at a later time in relation to the step of loading the first thermal storage. The duration of the delay is dependent on the application. If the method is being used to control peak demand for the colocalized process, loading and unloading may involve a regular daily demand pattern. However, for network applications, the delay can be more irregular.
    [00012] The loading and unloading steps of the first thermal storage can be carried out on a continuous or intermittent basis.
    [00013] The second thermal process or the first thermal process may include an energy storage device. The energy storage device may comprise a cryogenic energy storage device. Alternatively, the energy storage device may comprise an alternative thermal process, such as a compressed air energy storage device.
    [00014] The second process can be colocalized with the first process. If the second process comprises a CPSD, the first process can be, for example, thermoelectric stations and industrial processes such as steel and chemical production plants. The first thermal process may comprise heating directly from the thermal storage by means of a heating device powered by an intermittent renewable energy source or sources.
    [00015] A power storage device, by its nature, operates intermittently, that is, when there is a high demand for network power and thus power prices are high, or when there is a danger of the network falling and additional support is required . This intermittency of operation can be on an hourly, daily, weekly, monthly, seasonal or yearly basis. There is, therefore, a substantial difference in the ideal heat transfer rate between the first CPSD process and the second colocalized process (s).
    [00016] The present inventors have found that by installing thermal storage between the two processes, the receipt and supply of thermal energy can be better managed to improve the overall performance of the two systems. In particular, as CPSD requires heat and releases cold energy at typically more than 20 times the rate of a continuous colocalized process of similar energy capacity, thermal storage is required to optimize thermal performance.
    [00017] The first rate can be at least five times the second rate. The first rate can be at least ten times the second rate. The first rate can be at least twenty times the second rate.
    [00018] Thermal storage can have any of the functions revealed in GB1013578.8. In particular, thermal storage may comprise asymmetric thermal storage. Thermal storage can comprise: a first thermal mass; a second thermal mass; and a third thermal mass; where: the aspect ratios of at least two of the first, second and third thermal masses are different from each other; and an arrangement of ducts and valves configured to direct a heat transfer fluid to pass through a combination of one or more of the thermal masses, wherein the arrangement of ducts and valves is such that the thermal masses can be isolated from each other.
    [00019] In a preferred embodiment, the arrangement of ducts and valves is configured to enable the heat transfer fluid (HTF) to be directed through: i) all of the first, second and third thermal masses, and alternatively ii) two among the first, the second and the third thermal masses, and alternatively iii) one among the first, the second and the third thermal masses.
    [00020] The arrangement of ducts and valves can be such that the HTF can be directed through two of the first and the second thermal masses in parallel and the third thermal mass in series, and alternatively through two between the first and the second thermal masses in parallel.
    [00021] HTF can comprise a gas or a liquid. HTF is used to either heat or cool the thermal mass.
    [00022] A thermal mass is a substance that has the capacity to absorb and emit thermal energy.
    [00023] The thermal energy storage device can comprise more than three thermal masses.
    [00024] Each of the at least three thermal masses can comprise an individual thermal cell or a plurality of thermal cells arranged in parallel with each other. When one or more of the thermal masses comprise a plurality of thermal cells, each thermal cell within a thermal mass can have the same or different mean cross-sectional areas. When a thermal mass more than one thermal cell arranged in parallel with each other, the aspect ratio of the thermal mass is the ratio of the average length of the thermal cells to the sum of the flow area in average cross section of the thermal cells.
    [00025] The first, second and third thermal masses can comprise solid particles and the diameter of the particles in at least two of the first, the second and the third thermal masses can be different from each other. Alternatively, the diameter of the particles m at least two of the first, second and third thermal masses can be the same as each other. When referring to the particle diameter, the average equivalent spherical diameter of all particles within the thermal mass is represented.
    [00026] Each thermal cell may comprise one or a combination of: i) a bed filled with solid particles through which the HTF can pass directly to transport thermal energy to and from the thermal energy storage device, ii) a bed filled with solid particles arranged around at least one conduit through which the HTF can pass, iii) a solid mass "matrix" that includes a plurality of channels through which the HTF can pass, or iv) a volume of material phase change.
    [00027] When the first, second and third thermal masses comprise solid particles, the thermal cell can comprise one, or a combination, of options i) and ii).
    [00028] A phase change material is a material that has the capacity to store and release energy by changing its state, for example, from solid to liquid or liquid to gas and vice versa.
    [00029] In option ii), the stuffed bed is insulated from HTF at least one conduit.
    [00030] In options i) and ii), the particles can be spherical or almost spherical particles. The average equivalent spherical diameter of the particles is preferably 1 to 25 mm. Each thermal cell can include a plurality of solid particles that have the same equivalent spherical diameters, or different equivalent spherical diameters. In addition, or alternatively, each of the solid particles can be formed from different materials. The equivalent spherical diameters of the particles within each thermal cell can increase or decrease over the length of the thermal cell, from the input to the output. The material from which particles within each thermal cell are formed can change over the length of the thermal cell.
    [00031] The spherical average equivalent diameter of the particles in a thermal cell may be different from, or the same as, those in another thermal cell. By varying the diameter of the particles between the thermal masses, the pressure drop / heat transfer characteristics of the thermal storage can be optimized. Each thermal cell can have a circular, hexagonal, square, rhomboidal or any other shape that could easily be packed in a support structure.
    [00032] Each thermal mass can have a high thermal capacity to minimize the volume of the thermal mass.
    [00033] Preferably, each thermal mass has a low thermal conductivity. Preferably, each thermal mass has a thermal conductivity of less than 20 W / mK. More preferably, each thermal mass has a thermal conductivity of less than 5 W / mK. It is desirable that each thermal mass has a high thermal capacity for conductivity ratio. Preferably, each thermal mass has Cp * p / k> 180 s / mm, more preferably each thermal mass has Cp * p Zk> 500 s / mm, where Cp is the specific heat capacity, p is the density, and k is the thermal conductivity of the particles comprising the thermal mass. Rock is a preferred material for particles for each thermal mass. Preferably, the rock comprises granite, basalt or an artificial ceramic material. Alternatively, water in the form of ice could be used for the particles for each thermal mass. Preferably, the ice would not change its state through the operating range of the storage.
    [00034] The thermal energy storage device may additionally comprise a support structure for supporting thermal masses. The support structure can additionally support at least a portion of the duct and valve arrangement.
    [00035] The thermal energy storage device may further comprise insulation to isolate each thermal mass to minimize thermal losses of the thermal mass during storage.
    [00036] The insulation may comprise thermal insulating material applied to the interior of the support structure and / or thermal breaks between a base of the thermal mass and the support structure. Thermal breaks are layers of low conductivity material or overhead spaces that prevent heat conduction through thermal break. Each thermal cell can be isolated on its side. In a particular embodiment, the internal insulation comprises a double skin design in which the external support structure is isolated from the thermal mass or cells by an insulation layer and a thin inner skin in contact with the thermal mass or cells. Alternatively, a spray coating of the thermal insulating material can be applied to the interior of the support structure, or encapsulated insulating material can be fitted to the interior of the support structure.
    [00037] The thermal energy storage device may additionally comprise insulation to isolate the arrangement of ducts and valves to minimize thermal losses from the storage device.
    [00038] The isolation of thermal masses from each other helps to prevent losses by convection of the storage of thermal energy during the storage phase between loading and unloading. In particular, a valve can be provided at the entrance and exit of each thermal mass.
    [00039] The arrangement of ducts and valves can be such that the HTF can be directed through two or more of the thermal masses in series.
    [00040] The arrangement of ducts and valves can additionally be such that a first and second of the thermal masses are in parallel and a third of the thermal masses is in series with the first and the second thermal masses.
    [00041] The arrangement of ducts and valves can additionally be such that the HTF can be directed through two or more of the thermal masses in parallel.
    [00042] The aspect ratio of each thermal mass is the ratio of the average length of the thermal mass to the flow area in average cross section of the thermal mass. Thermal masses with different aspect ratios can be supplied by providing thermal masses of different area with medium cross section. Each of the thermal masses can have uniform cross-sectional areas along their length. Alternatively, each of the thermal masses can have variable cross-sectional areas along their length. For example, each of the thermal masses can have tapered cross sections. When a thermal mass comprises more than one thermal cell, one or more of the thermal cells can have tapered cross sections.
    [00043] The aspect ratios of at least two of the first, second and third thermal masses can be different from each other. Preferably, the aspect ratios of all three of the thermal masses are different.
    [00044] Preferably, the average cross-sectional area of the third thermal mass is smaller than the average cross-sectional area of the second thermal mass. Preferably the average cross-sectional area of the second thermal mass is smaller than the average cross-sectional area of the first thermal mass.
    [00045] Preferably, the last thermal mass through which the HTF flows during the final discharge has the smallest average cross-sectional area of the three thermal masses. In this case, such a smaller flow area in the final part of the storage during unloading allows the ideal thermal efficiency to be achieved.
    [00046] The thermal energy storage device can comprise more than three thermal masses.
    [00047] Each of the at least three thermal masses can comprise an individual thermal cell or a plurality of thermal cells arranged in parallel with each other. Preferably, the first thermal mass comprises more thermal cells than the second thermal mass which, in turn, comprises more thermal cells than the third thermal mass. In an exemplary embodiment, the first thermal mass comprises five thermal cells in parallel, the second thermal mass comprises four thermal cells in parallel, and the third thermal mass comprises an individual thermal cell.
    [00048] Thermal storage of the type described above may still be of benefit within other energy storage technologies, examples of which include, but are not limited to, the storage of adiabatic compressed air energy and Ericsson cycle technologies. Thermal storage can be integrated either within the storage device and / or between the storage device and a colocalized process.
    [00049] Figure 2 shows a CPSD 100 integrated with a colocalized thermal process 200 that donates heat, QH, and receives cold energy, Qc, through thermal stores 300 and 400 respectively.
    [00050] Furthermore, the present inventors have found that there are often several places in a colocalized process where heat can be extracted. The use of thermal storage to optimize the extraction rates of thermal energy can, if applied correctly, provide benefit to both processes.
    [00051] The first thermal energy can be generated by one or more sources of thermal energy. The first thermal energy may comprise heat energy, and the one or more sources of thermal energy may include one or more of: condensed steam from a thermoelectric or nuclear station, flue gas from a thermoelectric station; steam from a boiler; ambient air; soil heat (geological); and sea, river or lake water.
    [00052] The first source of thermal energy may comprise heating directly from the thermal storage by means of a heating device moved by a source or sources of intermittent renewable energy.
    [00053] For example, the first process may comprise a steam power plant. Many steam power plants reject significant amounts of low-grade heat through condensation of steam from the exhaust in the steam turbine. The extraction of heat before the condenser of the steam power plant for later use in the CPSD will reduce the parasitic load on the steam power plant by reducing the required air flow through the condenser. The integration of the CPSD with the steam power plant, therefore, benefits both processes: in providing 'free heat' to the CPSD, and in reducing the parasitic load (often referred to as accommodation load) in the power plant to steam. An example of such a process is shown schematically in Figure 3, in which the boiler 201 of the steam power plant vaporizes and overheats the working fluid, which drives the turbine 202 of the steam power plant. Heat is extracted from the exhausted working fluid of the turbine by means of heat exchanger 203. The working fluid is then condensed by the condenser 204 of the steam power plant with the aid of an air-driven fan (shown in dashed box 204) . The condensed working fluid is then pumped back to boiler 201 by means of boiler feed pump 205. Heat extracted from the process working fluid colocalized by heat exchanger 203 is stored in thermal storage 300 until required by CPSD 100 .
    [00054] However, condensate systems in steam power stations often operate at 30 to 70 ° C, limiting the temperature at which the process gas can be heated in the CPSD and, therefore, the efficiency of the CPSD. Preferably, the heat supplied to the CPSD would be at least 100 ° C, more preferably at 200 ° C. The additional ‘medium grade’ heat Qf can be extracted from the flue gas 206 of the steam power plant, as shown in Figure 3.
    [00055] The present inventors have discovered that it is beneficial to limit the amount of heat Qj that is extracted from the flue gas of a thermoelectric plant. If too much heat is extracted, the flue gas will fluctuate and will not disperse properly in the atmosphere, which can result in high ground level emissions close to the power plant. By extracting more of the required heat from the condensate system, only a small amount of energy needs to be drawn from the boiler tube, thus minimizing the impact on flue gas fluctuation and its consequences.
    [00056] The method of the present invention may further comprise: providing a second thermal storage; loading the second thermal storage with the second thermal energy from the second thermal process by transferring the second thermal energy to the second thermal storage at a third energy transfer rate; and discharging the second thermal storage by transferring the second thermal energy stored in the second thermal storage from the second thermal storage to components of a third thermal process and a fourth energy transfer rate, where the fourth rate is different from the third rate.
    [00057] The second thermal storage can have any of the functions described above. In particular, the second thermal storage may comprise asymmetric thermal storage.
    [00058] The second source of thermal energy may comprise heating directly from the thermal storage by means of a heating device powered by an intermittent source or sources of renewable energy.
    [00059] The third thermal process can be the same process as the first thermal process.
    [00060] The step of unloading the second thermal storage can be carried out at a later time in relation to the step of loading the second thermal storage.
    [00061] The step of unloading the second thermal storage can be carried out on a continuous and intermittent basis.
    [00062] The step of loading the second thermal storage can be carried out on a continuous and intermittent basis. The charging intermittency can be on an hourly, daily, weekly, monthly, seasonal or yearly basis.
    [00063] The fourth rate can be at least five times the third rate. The fourth rate can be at least ten times the third rate. The fourth rate can be at least twenty times the third rate.
    [00064] The second thermal energy can comprise heat energy or cold energy.
    [00065] When the first thermal process includes a cryogenic energy storage device, the first thermal energy may comprise cold energy released from the cryogenic energy storage device.
    [00066] The second thermal process can include one or more of: the air conditioning system for a building; the refrigeration unit in a manufacturing process; a gas liquefaction process; and cooling a data center.
    [00067] When the second thermal process includes a CPSD and a second thermal storage is provided, the second thermal energy may comprise cold energy released from the cryogenic energy storage device. In that case, the third thermal process may include one or more of: the air conditioning system for a building; the refrigeration unit in a manufacturing process; a gas liquefaction process; and cooling a data center. Brief Description of Drawings
    [00068] The modalities of the present invention will now be described with reference to the figures in which: Figure 1 shows the operating time of a typical power storage device; Figure 2 shows a CPSD integrated with a colocalized thermal process that donates heat and receives cold energy through thermal storage; Figure 3 shows an example of a CPSD integrated with a steam power plant; Figures 4a and 4b show Sankey diagrams for a cryogenic CPSD set on a power and energy basis, respectively; Figures 5a and 5b show Sankey diagrams for a gas engine on a power and energy basis, respectively; Figures 6a and 6b show the configuration of a CPSD cryogenic assembly, gas engine and thermal storage; Figure 7 shows a configuration of a CPSD cryogenic assembly with thermal storage and room vaporizer; Figure 8a) shows a thermal storage that can be used in the method of the present invention (the device is shown during a charging phase); Figure 8b) shows the thermal storage of Figure 8a) during an initial discharge phase; and Figure 8c) shows the thermal storage device of Figure 8a) during a final discharge phase. Detailed Description of the Invention
    [00069] Although the devices of WO 2007-096656 A1 and GB 1100569.1 are different, both benefit from receiving hot thermal energy and provide, when in operation, cold thermal energy and thus, in the context of the present invention, they are the same. For simplicity, the invention will be described through integration with a cryogenic CPSD set, but the same inventive principles would apply equally to a CES.
    [00070] Using the exemplary operating regime shown in Figure 1, a typical Sankey diagram for a cryogenic assembly in both a power base (Figure 4a) and an energy base (Figure 4b) is compared with a diagram of Typical Sankey for a 2 MW gas engine on both a power base (Figure 5a) and a power base (Figure 5b). The 2 MW gas engine of Figures 5a and 5b operates on a base load, such as at a landfill gas site or mine gas site where the installed engines are typically of the given capacities. It is evident that there is an incompatibility between the thermal power requirements (Figures 4a and 5a), but that the energy requirements (Figures 4b and 5b) are more compatible. In fact, it can be seen that, on an energy base, a 2 MW gas engine would support three 3.5 MW cryogenic sets: each 3.5 W cryogenic set requires 12.5 MWh of heat to generate 7 MWh net power (Figure 4b); the 2 MW gas turbines exhaust 41.28 Wh of heat (Figure 5b); which allows losses, on this basis the 41.28 Wh of exhaust heat from the gas turbine is sufficient for three cryogenic sets of 3.5 MW, each producing 7 MWh of net power.
    [00071] The present inventors have found that the installation of thermal storage between the two processes allows for a much better use of the energy flow between the two processes and the distribution of more useful storage capacity. For example, the modality shown in Figures 4 and 5 provides approximately an extra 10 W of useful storage capacity for a given level of base load heat generation in the colocalized process, which is a 2 MW gas engine in the example.
    [00072] However, although the introduction of thermal storage allows good use of the energy flow between the two processes, the incompatibility of the rate of the thermal loading and thermal unloading processes represents a particular challenge in the design of storage and in the integration of storage with the cryogenic ensemble and the heat generation process. In particular, thermal storage must have the capacity to receive heat at a rate of approximately 10% of the rate at which storage must supply heat to the cryogenic assembly. This difference inevitably results in a significant difference in the flow rate of the heat transfer media used to transport the thermal energy between the two processes and the thermal storage. A special type of 'asymmetric' thermal storage is described above. The inventors found that thermal storage that has this asymmetric operation is invaluable when it integrates an intermittent CPSD with a base load thermal source. Figures 8a) to 8c) show such an asymmetric thermal storage. Thermal storage includes three thermal masses of thermal storage material. The three thermal masses have different cross-sectional areas. The first thermal mass 1 has a greater average cross-sectional area than the second thermal mass 2 which, in turn, has a greater average cross-sectional area than the third thermal mass 3. Consequently, the device shown in Figures 8a ), b) and c) have a variable flow area.
    [00073] The device operates in the following manner:
    [00074] Loading: During loading, as shown in Figure 8a), the HTF flow passes through the first thermal mass 1 and then through thermal masses 2 and 3. Thermal masses 2 and 3 are arranged in parallel. Thermal mass 1 is arranged in series with thermal masses 2 and 3. The cross-sectional area of thermal mass 1 is chosen such that the ideal pressure drop / heat transfer ratio is achieved during loading.
    [00075] Storage: The thermal masses are isolated from each other to prevent losses by convection of the storage of thermal energy until the storage is discharged.
    [00076] Initial Discharge: During the initial discharge, as shown in Figure 8b), the HTF flow initially passes through thermal mass 1 and then thermal mass 2, with thermal mass 3 being ignored from the HTF flow circuit .
    [00077] Final Discharge: After undergoing the initial discharge for a period of time, thermal mass 2 will be discharged almost completely and the HTF outlet temperature will start to rise. During the final discharge, as shown in Figure 8c), thermal mass 1 is isolated from the circuit and the output flow of thermal mass 2 is directed through thermal mass 3. The cross-sectional flow area of thermal mass 3 is reduced in relation to those of thermal masses 1 and 2 in order to minimize final losses for the reduced discharge flow rate. The thermal mass 2 is then completely discharged and only a small mass of the material in the thermal mass 3 is not completely discharged. Thus, the amount of thermal energy that is not discharged from the thermal storage device is minimized. In some cases, it is not necessary to avoid thermal mass 1, thus simplifying the flow circuit if the pressure loss through thermal mass 1 is low.
    [00078] Figures 6a and 6b show through diagram how the gas engine 210 within a colocalized process 200, a cryogenic assembly 100 and a thermal storage 300 could be configured to achieve optimal efficiency. In this embodiment, the thermal storage 300 is charged by heat exchange with the exhaust stack 211 of the gas engine, by means of the exhaust heat recovery heat exchanger 212. During the loading of the thermal storage (Figure 6a), as the heat flow and the mass flow of the heat transfer fluid are low, the thermal storage cells 301, formed preferentially, but not exclusively, of the filled gravel beds, are arranged in series. In this configuration, the pressure drop across thermal storage 300 will be acceptable as the mass flow of fluid will be low. Final losses are minimized by the fact that the length-to-diameter ratio of thermal storage 300 is high as thermal storage cells 301 are arranged in series. During discharge (Figure 6b), still referred to as power recovery, the heat transfer rate and mass flow rate of heat transfer fluid needs to be higher than during charging; a series configuration of the storage 300 would result in an unacceptably high pressure drop. Consequently, instead of arranging the thermal storage cells 301 in series, the thermal storage cells 301 are arranged in parallel, thus presenting a larger flow area to the heat transfer fluid and, therefore, an acceptable flow speed within the thermal storage cells 301 and therefore an acceptable pressure drop.
    [00079] In the example described above, all thermal heat energy is supplied by the flue gas of a 210 gas engine. However, the invention is applicable to other sources of thermal heat energy. In the case shown in Figures 6a and 6b, as the engine 210 is small (only 2 MW), it is not economically viable to install a continuous heat recovery device, such as a lower steam set or an organic Rankine cycle (ORC) . Thermal energy is therefore available in 'medium grade', defined as greater than 100 ° C, but less than 250 ° C, in sufficient quantity for the CPSD 100. Higher power generation equipment such as a power plant from waste (EfW), Combined Cycle Gas Turbine (CCGT) and steam plant burning biomass or larger coal, with an output of the order of 30 MW to 50 MW and higher, will often be adjusted with stages of additional turbine or heat recovery equipment to improve the overall efficiency of the plant. The thermal energy in the exhaust stack is much lower and more heat is available in a low degree, defined as less than 100 ° C, for example, from the steam condenser, than in the example in Figures 6a and 6b. The integration of the thermal plant with the CPSD can be further optimized using heat from both sources. The inventors have found that low grade heat energy can provide 50% of the heat requirements for the preferred mode of a cryogenic assembly. This reduces the amount of medium grade heat that is required, which may be available in a smaller amount. Table 1 summarizes the amount of medium and low grade heat typically available from a number of competing thermal processes as a percentage of the process's classified electrical generation capacity: Table 1

    [00080] From the table above, it is evident that significantly more low grade heat is available than medium grade heat in the case of CCGT and EfW. In a preferred embodiment of the invention, medium-grade heat can be stored in a thermal buffer storage, and low-grade heat can be taken concurrently from the thermal source during discharge, or power recovery, of the cryogenic assembly. Such an arrangement allows a cryogenic assembly of greater capacity to be installed than would be possible without the use of thermal shock storage.
    [00081] In addition, the low-grade heat required by the cryogenic assembly can be further stored in a thermal shock storage. In such an arrangement, the use of low-grade heat can reduce the parasitic charge (or housing charge) on the thermal source by providing more effective means of rejecting the heat from the condensers than when using a cooled air condenser or cooling tower. cooling. The efficiency of the thermoelectric plant can therefore be improved.
    [00082] Low grade heat cannot be taken from the thermal source on a continuous basis. Instead, low-grade heat can be taken from the thermal source during the time of day when the ambient temperature is high, such as in the afternoon, and the parasitic charge to cool the condensing water is higher. Consequently, the maximum benefit of reducing the housing load at the thermal plant can be achieved.
    [00083] In some applications, the CPSD will not be located close to the heat source. The use of ambient heat during power recovery, such as through a heated air steamer alone, is impractical in the inventors' view because the thermal energy requirements during power recovery are very high. If it depends on the ambient heat alone, the fins of the vaporizer would need to be spaced apart to prevent ice build-up from moisture in the atmosphere, thus leading to a much larger heat transfer area. In the inventors' view, such a solution would be both expensive and would take up considerable soil area and would therefore not be profitable. Alternatively, with the method of the present invention, thermal storage can be used between the room vaporizer and the cryogenic assembly. Thermal storage can be heated using ambient heat at a low energy flow rate and a much smaller vaporizer. The thermal mass of the thermal storage can then be used during the power recovery phase of the CPSD to heat the cryogenic fluid to room temperature. A diagram of this embodiment of the invention is shown in Figure 7, in which the CPSD 100 is integrated with a heat storage 300 that is charged using ambient heat from the air by means of circulation pump 310 and heat exchanger 311. In embodiments Alternatively, ambient heat would be provided from the ground (geological heat), from a river or the sea.
    [00084] The inventors also note that both the Cryogenic Ensemble and the CES release considerable amounts of cold energy such as 'high grade cold' (typically below -150 ° C) and 'low grade cold' (typically between 0 ° C and -150 ° C). High and low grade cold energy is released in large quantities in a short period of time. Many processes require cooling and consume considerable amounts of power in an air conditioning and refrigeration plant. Examples of such processes are: • Data centers • Food storage depots • Supermarkets • Food processing plants • Telecommunications centers • Offices and commercial stores (for air conditioning)
    [00085] The connection of a CPSD with such applications can be used to reduce or even negate the need for air conditioning or refrigeration equipment, thus saving energy and capital costs. However, as cold energy is released from the CPSD in a short period of time, the use of a cold buffer storage is necessary in order to achieve the optimal performance of the integration of the two processes. Cold energy is then available to supply on a continuous basis to (for example) cool electronics in a data center or telecommunications center. In other applications, such as air conditioning in an office, it can be advantageous to capture cold energy from cold thermal storage on an intermittent basis, such as only when the office is open and there is a demand for cooling. The addition of cold thermal storage available makes it possible to use cold energy to be changed over time and the rate of cold supply to a final consumer to be changed regardless of the supply rate and supply time by the CPSD.
    [00086] It will be appreciated that the present invention has been described by way of example only and that changes or modifications can be made within the scope of the invention as defined in the following claims.
    权利要求:
    Claims (18)
    [0001]
    1. Method for integrating a first thermal process (200), a second thermal process (100) and a third thermal process (200), in which the heat transfer rate of the first thermal process (200) is different from the heat transfer from the second thermal process (100), the method comprising the steps of: providing a first thermal storage (300); manage reception of the first thermal energy by the first thermal storage (300) by loading the first thermal storage (300) with the first thermal energy of the first thermal process by transferring the first thermal energy to the first thermal storage (300) at a first rate of energy transfer; and managing a supply of the first thermal energy stored by the first thermal storage (300) by discharging the first thermal storage (300) by transferring the first stored thermal energy from the first thermal storage (300) to components of the second thermal process (100) in a second energy transfer rate, in which the second rate is different from the first rate, in which the method further comprises providing a second thermal storage (400); loading the second thermal storage (400) with second thermal energy from the second thermal process (100) by transferring the second thermal energy to the second thermal storage (400) at a third energy transfer rate; and discharge the second thermal storage (400) by transferring the second thermal energy stored in the second thermal storage (400) from the second thermal storage (400) to components of the third thermal process (200) at a fourth energy transfer rate, in which the fourth rate is different from the third rate, characterized by the fact that the first thermal storage (300) is an asymmetric thermal storage comprising a first thermal mass (1), a second thermal mass (2) and a third thermal mass (3), where the aspect ratios of at least two of the first (1), second (2) and third (3) thermal masses are different from each other, the aspect ratio being the ratio between the average length of the thermal mass and the flow area in average cross section of the thermal mass, and in which the arrangement of ducts and valves is such that the thermal masses can be isolated from each other; and wherein the steps of loading and unloading the first thermal storage (300) comprise passing a heat transfer fluid through a combination of one or more of the thermal masses.
    [0002]
    2. Method according to claim 1, characterized by the fact that the step of unloading the first thermal storage (300) is carried out at a later time in relation to the step of loading the first thermal storage (300).
    [0003]
    Method according to claim 1 or 2, characterized in that the step of loading and / or unloading the first thermal storage (300) is carried out on a continuous or intermittent basis.
    [0004]
    4. Method according to any of the preceding claims, characterized by the fact that the first rate is at least five times the second rate, preferably at least ten times the second rate, and more preferably at least twenty times the second rate.
    [0005]
    5. Method according to any one of the preceding claims, characterized by the fact that the first thermal energy comprises hot energy or cold energy.
    [0006]
    Method according to any one of the preceding claims, characterized in that the second thermal process (100) includes an energy storage device, preferably a cryogenic energy storage device or an air energy storage device compressed.
    [0007]
    7. Method according to any one of the preceding claims, characterized by the fact that the first thermal energy is generated by one or more sources of thermal energy, preferably by one or more among: condensed steam from a thermoelectric or nuclear station, gas combustion of a thermoelectric station; steam from a boiler; ambient air; soil heat (geological); and sea, river or lake water.
    [0008]
    8. Method according to any one of the preceding claims, characterized by the fact that the first thermal process (200) is the same process as the third thermal process (200).
    [0009]
    9. Method according to any one of the preceding claims, characterized by the fact that the step of unloading the second thermal storage (400) is carried out at a later time in relation to the step of loading the second thermal storage (400).
    [0010]
    10. Method according to any one of the preceding claims, characterized in that the step of loading and / or unloading the second thermal storage (400) is carried out on a continuous or intermittent basis.
    [0011]
    11. Method according to any one of the preceding claims, characterized by the fact that the fourth rate is at least five times the third rate, preferably at least ten times the third rate, and more preferably at least twenty times the third rate.
    [0012]
    12. Method according to any one of the preceding claims, characterized in that the second thermal energy comprises hot energy or cold energy.
    [0013]
    13. Method according to any one of the preceding claims, characterized in that the first source includes an energy storage device, preferably a cryogenic energy storage device, or an adiabatic compressed air energy storage device or an Ericsson cycle compressed air energy storage device.
    [0014]
    14. Method according to claim 13, characterized by the fact that the first thermal energy comprises cold energy released from the cryogenic energy storage device.
    [0015]
    15. Method according to claim 14, characterized by the fact that the second thermal process (100) includes one or more of: the air conditioning system for a construction; the refrigeration unit in a manufacturing process; a gas liquefaction process; and cooling a data center.
    [0016]
    16. Method according to claim 6 or 7, characterized in that the second thermal energy comprises cold energy released from the cryogenic energy storage device.
    [0017]
    17. Method according to claim 16, characterized by the fact that the third thermal process (200) includes one or more of: the air conditioning system for a construction; the refrigeration unit in a manufacturing process; a gas liquefaction process; and cooling a data center.
    [0018]
    18. Method according to any one of the preceding claims, characterized in that the second thermal storage (400) comprises an asymmetric thermal storage.
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    同族专利:
    公开号 | 公开日
    DK2603762T3|2020-01-20|
    CN103119390A|2013-05-22|
    US20130284394A1|2013-10-31|
    DK2603761T3|2017-11-13|
    US9377247B2|2016-06-28|
    EP2603762A2|2013-06-19|
    AU2011288289A1|2013-03-14|
    BR112013003389B1|2020-12-08|
    CN103119390B|2017-06-20|
    WO2012020234A3|2012-09-27|
    ZA201300827B|2014-04-30|
    GB201304433D0|2013-04-24|
    ES2764831T3|2020-06-04|
    WO2012020234A2|2012-02-16|
    CN103069247B|2017-03-22|
    EP2603761B1|2017-10-11|
    BR112013003382A2|2016-07-12|
    US10012447B2|2018-07-03|
    GB2497045A|2013-05-29|
    GB2497045B|2015-01-07|
    AU2011288289B2|2014-06-19|
    US20130240171A1|2013-09-19|
    ES2645341T3|2017-12-05|
    EP2603761A2|2013-06-19|
    PL2603761T3|2018-02-28|
    BR112013003389A2|2016-07-12|
    PL2603762T3|2020-06-15|
    CL2013000339A1|2014-05-02|
    EP2603762B1|2019-10-23|
    AU2011288290A1|2013-03-14|
    WO2012020233A3|2012-09-27|
    AU2011288290B2|2015-04-09|
    ZA201300828B|2014-04-30|
    WO2012020233A2|2012-02-16|
    CN103069247A|2013-04-24|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    BE639323A|1962-11-05|
    GB1100569A|1966-02-08|1968-01-24|Dow Chemical Co|A process for preparing acrylic latexes|
    US4173125A|1978-03-16|1979-11-06|Schweitzer Industrial Corporation|Energy recovery system|
    DE2960572D1|1978-06-16|1981-11-05|Ciba Geigy Ag|Means for providing heated water by solar energy|
    US4418683A|1981-04-23|1983-12-06|Rockwell International Corporation|Separated phase thermal storage system|
    JPH0329977B2|1982-03-26|1991-04-25|
    JPS58165550U|1982-04-27|1983-11-04|
    JPH0271055A|1988-09-07|1990-03-09|Kawasaki Heavy Ind Ltd|Compressed air energy storage system|
    FR2665945A1|1990-08-17|1992-02-21|Schmid Ing Sa Nles Applic Scie|Device for storing cold|
    US5271239A|1990-11-13|1993-12-21|Rocky Research|Cooling apparatus for electronic and computer components|
    JP2641701B2|1994-09-21|1997-08-20|有限会社白井商事|Solar heat storage device and hot water supply system including the device|
    FR2847973B1|2002-11-29|2006-01-27|Valeo Climatisation|THERMAL INERTIAL HEAT EXCHANGER FOR A HEAT PUMP CIRCUIT, IN PARTICULAR A MOTOR VEHICLE.|
    IL155665A|2003-04-29|2009-05-04|Pessach Seidel|Thermal energy storage|
    CA2643742C|2006-02-27|2014-08-26|Haisheng Chen|A method of storing energy and a cryogenic energy storage system|
    US20080066736A1|2006-07-25|2008-03-20|Yanong Zhu|Method and apparatus for solar energy storage system using gas and rock|
    MX2009009627A|2007-03-08|2009-11-26|Univ City|Solar power plant and method and/or system of storing energy in a concentrated solar power plant.|
    JP5240501B2|2007-03-19|2013-07-17|株式会社リコー|Ink set, ink cartridge, ink jet recording method, and ink jet recording apparatus|
    US7877999B2|2007-04-13|2011-02-01|Cool Energy, Inc.|Power generation and space conditioning using a thermodynamic engine driven through environmental heating and cooling|
    US7942018B2|2008-02-01|2011-05-17|The Hong Kong Polytechnic University|Apparatus for cooling or heating thermal storage using microencapsulated phase change material slurries|
    CN102016483A|2008-04-29|2011-04-13|开利公司|Modular heat exchanger|
    ES2306628B2|2008-06-26|2009-10-15|Universidad Politecnica De Madrid|DEVICE AND PROCEDURE OF LOW ENTROPIA THERMAL STORAGE.|
    US8063609B2|2008-07-24|2011-11-22|General Electric Company|Method and system for extending life of a vehicle energy storage device|
    US20100089391A1|2008-10-13|2010-04-15|Addie Andrew R|System and process for using solar radiation to produce electricity|
    EP2275649B1|2009-06-18|2012-09-05|ABB Research Ltd.|Thermoelectric energy storage system with an intermediate storage tank and method for storing thermoelectric energy|
    WO2011047086A2|2009-10-14|2011-04-21|Infinia Corporation|Systems, apparatus and methods for thermal energy storage, coupling and transfer|
    US9377247B2|2010-08-12|2016-06-28|Highview Enterprises Limited|Integration of an energy storage device with a separate thermal process|US9377247B2|2010-08-12|2016-06-28|Highview Enterprises Limited|Integration of an energy storage device with a separate thermal process|
    GB201104867D0|2011-03-23|2011-05-04|Isentropic Ltd|Improved thermal storage system|
    GB201207114D0|2012-04-23|2012-06-06|Isentropic Ltd|Improved thermal energy storage apparatus|
    WO2013167158A1|2012-05-11|2013-11-14|Vladan Petrovic|Long-term heat storage device and method for long-term heat storage of solar energy and other types of energy with changing availability|
    JP2014047992A|2012-08-31|2014-03-17|Hitachi Ltd|Heat storage system and power generating system having the same|
    FR2998556B1|2012-11-28|2015-12-18|Electricite De France|CONTAINER FOR HEAT STORAGE MATERIAL WITH REINFORCED STRUCTURE.|
    WO2014174373A2|2013-04-25|2014-10-30|Mada Energie Ltd|Energy processing and storage|
    CN103388999B|2013-06-25|2015-01-28|中国科学院工程热物理研究所|Spray packed bed heat storage device|
    EP3071892A4|2013-10-24|2017-08-30|Research Foundation Of The City University Of New York|Methods for meeting localized peak loads in buildings and urban centers|
    US20150144304A1|2013-11-28|2015-05-28|Enolcon Gmbh|High-temperature thermal storage device with induction heating and molten metal, and thermal storage-composite system|
    WO2015106815A1|2014-01-16|2015-07-23|Siemens Aktiengesellschaft|Heat reservoir comprising a diffusor portion|
    CN103712255B|2014-01-20|2015-12-30|华北电力大学|A kind of releasing across solar energy-phase-changing energy-storing classification in season can heating system and method|
    ES2748557T3|2014-04-16|2020-03-17|Siemens Gamesa Renewable Energy As|Passive way to improve heat distribution in compact bed storage|
    DE102014208454A1|2014-05-06|2015-11-12|Siemens Aktiengesellschaft|heat storage|
    GB201409669D0|2014-05-30|2014-07-16|Highview Entpr Ltd|Improvements in air purification units|
    DE102015009256A1|2015-07-16|2017-01-19|Linde Aktiengesellschaft|Fixed bed cold store and method for storing thermal energy|
    ES2747778T3|2015-09-30|2020-03-11|Siemens Gamesa Renewable Energy As|Heat exchange system with at least two heat exchange chambers and procedure for exchanging heat using the heat exchange system|
    US11022381B2|2015-09-30|2021-06-01|Siemens Gamesa Renewable Energy A/S|Heat exchange system with main heat exchange chamber and subsidiary heat exchange chamber and method for exchanging heat by using the heat exchange system|
    WO2017055409A1|2015-09-30|2017-04-06|Siemens Aktiengesellschaft|Heat exchange system with a heat exchange chamber in with a thermal insulation layer, method for manufacturing the heat exchange system and method for exchanging heat by using the heat exchange system|
    DE102016001163A1|2016-02-03|2017-08-03|Karl Brotzmann Consulting Gmbh|Method and device for receiving, storing and emitting thermal energy of gases|
    US20200191500A1|2016-05-20|2020-06-18|Kansas State University Research Foundation|Methods and systems for thermal energy storage and recovery|
    WO2017210555A1|2016-06-03|2017-12-07|Board Of Regents, The University Of Texas System|High-density latent heat storage device|
    US10508596B2|2017-06-21|2019-12-17|John D. Upperman|System and method for liquid air energy storage|
    EP3714228A4|2017-11-21|2021-08-11|Aestus Energy Storage, LLC|Heat sink vessel|
    FR3083596A1|2018-07-06|2020-01-10|L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude|PROCESS AND PLANT FOR COLLECTING AND STORING COLD GASES FROM CRYOGENIC EQUIPMENT|
    CN109764511B|2019-01-09|2021-08-24|重庆海尔空调器有限公司|Control method of energy system|
    CN109855459B|2019-01-09|2021-01-29|青岛海尔空调器有限总公司|Control method of energy system|
    CN109737619B|2019-01-09|2021-04-20|青岛海尔空调器有限总公司|Control method and device of energy system, computer equipment and storage medium|
    JP2021014836A|2019-07-16|2021-02-12|株式会社日本クライメイトシステムズ|Vehicular heat storage system|
    CN110822967B|2019-09-30|2021-07-13|西安交通大学|Integral structure for adsorption type thermochemical energy storage and building heating|
    US11035260B1|2020-03-31|2021-06-15|Veritask Energy Systems, Inc.|System, apparatus, and method for energy conversion|
    WO2021257731A1|2020-06-16|2021-12-23|Cyrq Energy, Inc.|Electricity generating systems with thermal energy storage coupled superheaters|
    法律状态:
    2018-12-26| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|
    2019-10-01| B06U| Preliminary requirement: requests with searches performed by other patent offices: suspension of the patent application procedure|
    2020-06-23| B09A| Decision: intention to grant|
    2020-11-10| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 12/08/2011, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    GBGB1013578.8A|GB201013578D0|2010-08-12|2010-08-12|Method and apparatus for storing thermal energy|
    GB1013578.8|2010-08-12|
    GBGB1104387.4A|GB201104387D0|2011-03-15|2011-03-15|Integration of an energy storage device with a separate thermal process|
    GB1104387.4|2011-03-15|
    PCT/GB2011/001215|WO2012020234A2|2010-08-12|2011-08-12|Integration of an energy storage device with a separate thermal process|
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